Techniques for locating the screw access hole in cement-retained implant-supported prostheses: A systematic review.

STATEMENT OF PROBLEM: Different techniques for retrieving cement-retained implant-supported prostheses have been described to minimize damage to the prostheses. Nevertheless, a classification of the described techniques remains ambiguous. PURPOSE: The purpose of this systematic review was to review and classify the described techniques for recording and locating the screw access hole in cement-retained implant-supported prostheses. MATERIAL AND METHODS: A bibliographic search was completed on MEDLINE/PubMed, Web of Science, Scopus, and Cochrane databases. A manual search was also conducted. The articles that described or evaluated techniques for recording and locating the screw access hole of cement-retained implant-supported prostheses were included. Two investigators independently assessed the quality assessment of the studies using the Revised Cochrane risk of bias tool for randomized trials. A third examiner was consulted to resolve the lack of consensus. RESULTS: A total of 30 articles were included. The different methods were classified according to whether the screw access hole location was registered before or after cementation. The precementation techniques were classified into 4 subgroups: identification marks, photographic records, digital files, and precementation screw access hole location guides. The postcementation techniques were subdivided into 2 subgroups: radiographic records and postcementation screw access hole location guides. CONCLUSIONS: Different techniques have been proposed to facilitate the location of the screw access hole in cement-retained implant-supported restorations. Although the evidence is scarce, studies seem to ascertain that some techniques, such as the use of drilling guides, orientation with cone beam computed tomography images, or holes made in the metal framework, can increase the retrievability of cement-retained implant-supported prostheses and decrease complications in the location of the screw access hole. The proposed classification summarizes precementation and postcementation techniques and provides a tool to decide the most suitable for each specific clinical situation.

Degradation of the herbicide 2,4-DP by anodic oxidation, electro-Fenton and photoelectro-Fenton using platinum and boron-doped diamond anodes.

This paper reports the degradation of 2,4-DP (2-(2,4-dichlorophenoxy)-propionic acid) solutions of pH 3.0 by environmentally friendly electrochemical methods such as anodic oxidation, electro-Fenton and photoelectro-Fenton with a Pt or boron-doped diamond (BDD) anode. In the two latter techniques an O(2)-diffusion cathode was used and 1.0mM Fe(2+) was added to the solution to give hydroxyl radical (*OH) from Fenton's reaction between Fe(2+) and H(2)O(2) generated at the cathode. All treatments with BDD are viable to decontaminate acidic wastewaters containing 2,4-DP since they give complete mineralization, with loss of chloride ion, at high current due to the great production of oxidant *OH at the BDD surface favoring the destruction of final carboxylic acids. *OH formed from Fenton's reaction destroys more rapidly aromatic products, making the electro-Fenton and photoelectro-Fenton processes much more efficient than anodic oxidation. UVA light in photoelectro-Fenton with BDD has little effect on the degradation rate of pollutants. The comparative procedures with Pt lead to slower decontamination because of the lower oxidizing power of this anode. The effect of current on the degradation rate and efficiency of all methods is studied. The 2,4-DP decay always follows a pseudo-first-order kinetics. Chlorohydroquinone, chloro-p-benzoquinone and maleic, fumaric, malic, lactic, pyruvic, acetic, formic and oxalic acids are detected as products by chromatographic techniques. A general sequence accounting for by the reaction of all these intermediates with the different oxidizing agents is proposed.

Electrochemical degradation of chlorophenoxy and chlorobenzoic herbicides in acidic aqueous medium by the peroxi-coagulation method.

The degradation of 4-chlorophenoxyacetic acid (4-CPA), 4-chloro-2-methylphenoxyacetic acid (MCPA), 2,4-dichlorophenoxyacetic acid (2,4-D) and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) as chlorophenoxy herbicides, as well as of 3,6-dichloro-2-methoxybenzoic acid (dicamba) as chlorobenzoic herbicide, has been studied by peroxi-coagulation. This electrochemical method yields a very effective depollution of all compounds in acidic aqueous medium of pH 3.0 working under pH regulation, since they are oxidized with hydroxyl radicals produced from Fenton's reaction between Fe(2+) and H(2)O(2) generated by the corresponding Fe anode and O(2)-diffusion cathode. Their products can then be removed by mineralization or coagulation with the Fe(OH)(3) precipitate formed. Both degradative paths compete at low currents, but coagulation predominates at high currents. The peroxi-coagulation process of dicamba at I>or=300 mA leads to more than 90% of coagulation, being much more efficient than its comparative electro-Fenton treatment with a Pt anode and 1 mM Fe(2+), where only mineralization takes place. For the chlorophenoxy compounds, electro-Fenton gives a slightly lower depollution than peroxi-coagulation, because more easily oxidable products are produced. Oxidation of chlorinated products during peroxi-coagulation is accompanied by the release of chloride ion to the solution. The efficiency of this method decreases with increasing electrolysis time and current. The decay of all herbicides follows a pseudo-first-order reaction, with a similar constant rate for 4-CPA, MCPA, 2,4-D and 2,4,5-T, and a higher value for dicamba.